PREFACE 1 INTRODUCTION TO INORGANIC CHEMISTRY 1-1 What is Inorganic Chemistry? 1-2 Contrasts with Organic Chemistry 1-3 Genesis of the Elements (The Big Bang)and Flrmation of the Earth 1-4 Nuclear Reactions and Radioactivity 1-5 Distribution of Elements on Earth 1-6 The History of Inorganic Chemistry
2 ATOMIC STRUCTURE 2-1 Historical Development of Atomic Theory 2-1-1 The Periodic Table 2-1-2 Discover of Subatomic Particles and the Bohr Atom 2-2 The Schrodinger Equation 2-2-1 The Particle in a Box 2-2-2 Quantum Numbers and Atomic Wave Functions 2-2-3 The Aufbau Principle 2-2-4 Shielding 2-3 Perildic Properties of Atoms 2-3-1 Ionization Energy 2-3-2 Elecrton Affinity 2-3-3 Covalent and Ionic Radii
3 SIMPLE BONDING THEORY 3-1 Liewis Electron-Dot Diagrams 3-1-1 Resonance 3-1-2 Expanded shells 3-1-3 Formal Charge 3-1-4 Multiple Bonds in Be and B Compounds 3-2 Valence Shell Electron Pair Repulsion Theory 3-2-1 Lone Pair Repulsion 3-2-2 Multiple Bonds 3-2-3 Electroneatuvity and Atomic Size Effects 3-2-4 Ligand Close-Packing 3-3 Polar Molecules 3-4 Hydrogen Bonding
4 SYMMETRY AND GROUP THEORY 4-1 Symmetry Element and Operations 4-2 Point Groups 4-2-1 Groups of Low and High Symmetry 4-2-2 Other Groups 4-3 Properties and Representations of Groups 4-3-1 Matrices 4-3-2 Representations of Point Groups 4-3-3 Character Tables 4-4 Examples and Applications of Symmetry 4-4-1 Chirality 4-4-2 Molecular Vibrations
5 MOLECULAR ORBITALS 5-1 Formation of Molecular Orbiatls form Atomic Orbitals 5-1-1 Molecular Orbitals form s Orbitals 5-1-2 Molecular Orbitals form p Orbitals 5-1-3 Molecular Orbitals form d Orbitals 5-1-4 Nonbonding Orbitals and Other Factors 5-2 Homonuclear Diatomic Molecules 5-2-1 Molecular Orbitals 5-2-2 Orbitals Mixing 5-2-3 First and Second Row Mocecules 5-2-4 Photoelectron Spectroscopy 5-2-5 Correlation Diagrams 5-3 Heteronuclear Diatomic Molecules 5-3-1 Polar Bonds 5-3-2 Ionic Compounds and Molecular Orbiatals 5-4 Molecular Orbitals for Larger Molecules 5-4-1 FHF 5-4-2 CO2 5-4-3 H2O 5-4-4 NH3 5-4-5 BF3 5-4-6 Molecular shapes 5-4-7 Hybrid Orbitals 5-5 Expanded Shells and Molecular Orbitals
6 ACID-BASE AND DONOR-ACCEPTOR CHEMISTRY 6-1 Acid-Base Concepts as Organizing Concepts 6-1-1 History 6-2 Major Acid-Base Concepts 6-2-1 Arrhenius Concept 6-2-2 Brnsted-Lowry Concept 6-2-3 Solvent System Concept 6-2-4 Lewis Concept 6-2-5 Frontier Orbitals and Acid-Base Reactions 6-2-6 Hydrogen Bonding 6-2-7 Electronic Spectra(Including Charge Transfer) ……
7 THE CRYSTALLINE SOLID STATE 8 CHEMISTRY OF THE MAIN GROUP ELEMENTS 9 COORDINATION CHEMISTRYⅠ:STRUSTURES AND ISOMERS 10 COORDINATION CHEMISTRYⅡ:BONDING 11 COORDINATION CHEMISTRYⅢ:ELECTRONIC SPECTRA 12 COORDINATION CHEMISTRYⅣ:REACTIONS AND MECHANISMS 13 ORGANOMETALLIC CHEMISTRY 14 ORGANOMETALLIC REACTONS AND CATALYSIS 15 PARALLELS BETWEEN MAIN GROUP AND ORGANOMETALLIC CHEMISTRY 16 BIOINORGANIC AND ENVIRONMENTAL CHEMISTRY APPENDIXA ANSWERA TO EXERCISES APPENDIXA B-1 IONIC RADII APPENDIXA B-2 IONIZATION ENERGY APPENDIXA B-3 ELECTORON AFFINITY APPENDIXA B-4 ELECTRONEGATIVITY APPENDIXA B-5 ABSOLUTE HARDNESS PARAMETERS APPENDIXA B-6 CA,EA,CB,AND EB VALUES APPENDIXA B-7 LATIMER DIAGRAMS FOR SELECTED ELEMENTS APPENDIXA C CHARACTER TABLES APPENDIXA ELECTRON-DOT DIAGRAMS AND FORMAL CHARGE INDEX